My research focuses on global climate change and the use of isotope geochemistry to understand climatic and atmospheric processes. I am interested in the parameters and mechanisms that control paleotemperature proxies; in particuler, my group develops and uses the novel proxy carbonate clumped isotopes. We examine biological parameters that affect clumped isotopes and develop its use in new archive materials; we study the effect of non equilibrium processes on clumped isotopes and oxygen isotopes. We apply clumped isotpes to reconstruct paleotemperature and paleo-rainfall in different time periods during the Cenzoic. I am also interested in the use of isotopes to understand the modern carbon cycle and the effect of the biosphere of atmospheric chemistry.
What is clumped isotopes geochemistry?
Analysis of an isotopic composition is a measurement of the relative abundance of a heavy, rare, isotope within a group of molecules. The term ‘clumped isotopes’ refers to the natural abundance of molecules containing two heavy isotopes, such as 13C18O16O, and is a measure of the preference of two heavy isotopes to clump together into a chemical bond. This preference is temperature dependent with the isotopes distributed randomly among all molecules at very high temperatures and are clustered together into a more ordered system at low temperatures.
This results in an isotopic parameter, ∆47, that can record the temperature in which these bonds were formed. ‘Clumped isotopes’ measurements are currently applied for 13C-18O bonds in CO2 molecules that are extracted either from carbonate minerals or from the atmosphere. In carbonates ‘clumped isotopes’ are used to determine the formation temperature of the mineral with most applications associated with reconstruction of past climatic conditions. In atmospheric CO2 it is used as a tracer for partitioning and quantifying the different CO2 sources and sinks of the global carbon cycle.